There is a fundamental minimum amount of energy needed to desalinate: you can't take less energy to do it,than you could gain back (from osmotic pressure) if you allowed the desalinated water to expand a cylinder containing the residual brine. This is large. This paper is a thermal method, so it doesn't have an electricity input, but to justify their efficiency claim, they should really compare against what you could do by using the same surface area for solar panels, driving a conventional setup. My (limited) understanding is that conventional reverse osmosis is not far from the theoretical optimum, energy-wise, the main difficulties being operational (the membranes need declogging). And of course RO is more expensive than rain.
This paper is interesting, however, in directly producing crystalline salt, which is lower volume than brine and easier to dispose of, maybe even valuable.
If this can be applied to mine effluent, you could replace the maybe with most certainly. Sulfuric acid effluent lakes leech all sorts of valuable metals out of the ground.
You could just dilute it using fresh seawater, if you used enough and (maybe) spread it over a wider area. The amount of water people need for drinking is a relative drop in the ocean.
In an ideal world that crystalline salt by product could be used to offset any imported or mined salt, further reducing the environmental impact of those operations.
They're still at lab scale in glass. They haven't built a usable system, even a small one. The big claim here is that it doesn't clog; capillary action moves the salt out of the active area to another area, where some yet to be developed mechanism removes it. That needs to be demonstrated.
If they can come up with something that runs for years without clogging or replacing the active material, that's a real advance.
Laser surface preparation is known.[2] It's useful for roughening smooth surfaces in a very structured way, in preparation for painting. The result is a smooth paint surface. If you sandblast to roughen, the first paint layer is somewhat irregular. Then you need to sand and paint again to get a smooth surface. Laser roughening has been tried for auto painting, but didn't go mainstream. A good question here is whether commercial laser surface prep systems can make the material this new process uses.
It reminds me of how the Panama canal was built, and actually the first major attempt failed and they gave up. What they learned for the second attempt was that digging was not the hard(est) part to solve - it was how to move the dirt! So much dirt!
Great book on this BTW: Path Between the Seas. I couldn't put it down.
Fragility is a common problem in surface treatments, sometimes called "nanotechnology". There are super hydrophobic surface treatments that are very effective.
They generate a surface which is a forest of tiny sharp points. The surface tension of water is too high to cling to such a surface. You can make something that just will not get wet.
The problem is that the points are fragile, and wear destroys the effect.
Another example is ultra black coatings. Those are a forest of tiny black objects arranged so that light gets reflected multiple times and is absorbed. The commercial version is called "Vantablack". It doesn't wear well, but for optical applications such as the insides of camera lenses and telescopes, that's fine.
It's such a good book! Like any dad reading history, I have been annoying my family for years with fun facts I learned in that book. David McCullough's other books like The Great Bridge (about building the Brooklyn Bridge) are also great.
This is an interesting tech, but I have big doubts. In the picture you can see some salt coating the surface. Even just a little seems like too much for this type of system. I really hope they can make this work and scale this up.
Always wondered why the coast of the Red Sea isn't littered with channels which get flooded with seawater, which then evpporate into glassed ceilings; creating freshwater, and leaving behind salts for mining.
Combined with some mangrove farms, surely desert coasts are able to support more life.
Wonder if this is scalable tech, and how quickly it can 'process' water. I guess if they're combined with transparent solar panels, it could be quite an epic tech.
So crazy question: take a dehumidifier, attach some solar panels, and deploy at scale for non-potable water suitable for crop irrigation anywhere that isn't a desert. Does it work? And if not, why?
It takes too much energy and produces water too slowly to scale. In general any area with sufficient moisture in the air to explore this also has easier access to rain and ground water.
Great point, in my case in the PNW, the water from my local well is infested with manganese (as in clogging the household plumbing in the absence of a sediment filter) and other contaminants and the water company providing it is owned by private equity. Legally, I can drill my own well for non-potable irrigation, but god forbid I filter and/or chlorinate it for my own household use. So I end up considering options like this, thanks for debunking.
At the very least I would UV disinfect anything coming from the ground and absolutely make use of a 20 micron sediment filter if only to address cognitive load: Another place, another time, coliform bacteria from the well. Super fun(not).
It "works" in the sense that this is what 99% of "Get water from air" scams are.
The reason it doesn't actually work is that it is extremely inefficient. Getting water to condense requires you to somehow reject massive quantities of heat. That's fundamental to physics.
Also, literally anywhere a dehumidifier is reasonably effective, is humid and usually doesn't have such dire water problems. Deserts have extremely low humidity and dehumidifiers working in a desert will produce very little water.
Even a good humidifier in a humid environment is burning KW to generate on the order of ten liters of water a day.
There are a couple places on earth that are essentially deserts but have an early morning humid fog roll through regularly, and those places figured out capturing that water in the air long long before we invented the refrigeration cycle.
It is literally cheaper to desalinate.
Maybe you could build giant greenhouses to fill with sea water and let the sun evaporate the water and collect that with a dehumidifier? Still absurdly inefficient. Water has such an obscene specific capacity for heat that any thermal avenue of separating it from something else will use immense energy.
What do you mean work? No, because there is no single dehumidifier on the market that will get you enough water, so you are out $80 grand, you could have just paid for water delivery.
If true then this might be indeed a game changer, but numerous
academic publications turned out to be unfit for upscaling.
Who all has access to a femto laser? As far as I know these are
all patented, and most of those patents (or at the least companies
with rights to production) are in the USA, according to a professor
who told us so some years ago in university (in central Europe, but
he is quite old already, so I am not sure if his information was 100%
up to date; but otherwise I do not doubt the validity of his claim
made). So someone is going to milk rather than help. Will be interesting
to see what happens to that in some years. My current guesstimate is
that nothing will really happen or change.
you can now extract (like mining) minerals from the ocean, sounds kind of dangerous for the ecosystem maybe? making it profitable to extract magnesium, lithium, salt... we can probably guess how this story goes.
You're worried we might use all the salt in the sea for some kind of ... salt pyramids, send the water back out through sewers, and consequently leave the world's oceans diluted? That's about 1 followed by 21 zeroes, I think, in liters.
They are talking about lithium recovery, but there is a less exotic byproduct I'm interested in. One tonne (≈ 1 m^3) of seawater contains about 1.3 kilograms of magnesium, equivalent to about 4 kg of magnesite ore. Typical desal prices are on the order of $1 per tonne. Magnesite ore goes for about $100 per tonne, so the crude magnesium in a tonne of seawater is worth about $0.40, which could account for a substantial fraction of the desalination cost. (These numbers are very rough.)
Now you ask: why don't we just recover magnesium from brines if it's so great? Magnesium recovery from seawater isn't that easy: typically you have to treat it with some kind of alkali (often Ca(OH)2), so the cost is dominated by the extraction process (your alkali is consumed!), and you're competing with a pretty cheap ore. But if you have a solid byproduct, instead of a liquid, the options for magnesium recovery might be a lot more efficient, potentially offsetting the cost.
The fourth-most-prevalent ion, sulfate, might also be interesting, at least in a hypothetical post-petroleum future where sulfur as a byproduct of fossil fuel extraction is no longer "free". Sulfate is also annoying to extract from seawater, but again if we have a solid, the rules change.
As for the "table" salt itself, I think we'd quickly saturate (!) the market.
Calcining Mg(OH)₂ -which is what you find in seawater -
converts the soft compound into magnesium oxide, a valuable mineral commonly used in refractories, catalysts, and ceramics.The Chemical Equation: \(Mg(OH)_2 \xrightarrow{\Delta} MgO + H_2O\)Temperature Requirements: You need to heat the magnesium hydroxide to a temperature range between 500°C and 900°C. Heating at the lower end (around 500°C) yields a highly reactive, porous form of nano-MgO, while heating above 1,200°C creates "dead-burned" MgO used in high-heat industrial bricks.The Yield: The weight of your final MgO product will be roughly 69% of the original Mg(OH)₂ mass, as the evaporated water accounts for the 31% weight difference.
Already energy intensive. To get to magnesium ore is another step.
After looking at the paper, this looks like the core result:
“We collected a total of 9.3 g freshwater along with 0.343 g of sea salt from the ABF-STIC with a 9 cm2 surface area over the course of 9 hours. This is equivalent to generating 10.33 liters m−2 of freshwater and 0.38 kg m−2 of sea salt per day. The salinity of the desalinated water is found well below the WHO and EPA standards for safe drinking water.”
However the enclosure system required looks rather complicated and might be sensitive to external temperature (maybe a solar PV-powered cooling loop would help) and I imagine the cost-per-square-meter of the material is rather high, so this looks more like something for emergency response situations or maybe a desal system for a mega-yacht. If it could be scaled the idea is interesting, maybe as lithium separation from concentrated geological brines?
Persian Gulf has 20% more salt in water because of the humans which are throwing the oversalinated waste back into the sea. Dehidrated salt may be a big deal for some areas because of no waste into input.
Through the magic of Googling "Persian Gulf salinity" it seems like it's more that it's a shallow Gulf in a dry area so it has significant evaporation. Desalination does effect it but it's only a few percent of the total evaporation (which is still surprisingly big) and doesn't sound like the main driving factor or an imminent ecological concern.
Sure, but typically desalination plants are located in a single physical place, so a discharge pipe dumping brine 24x7 is bad for all of the things around it, as the local concentration is extremely high.
I wonder what the linear diffusion gradient would look like for that. Like the perforated garden hoses or whatever for soaking soil. Aquatic organisms grow so quick though very curious on the constraints for something like this.
I liked the idea of loading it up on a ship that sails out releasing as it goes out and back. Make it solar powered or even go old school with literal sails.
I thought they tend to pipe far out and discharge as far below the surface as possible, since there is a lot of surface life and it is less damaging this way.
Ships (with long submerged pipes) would be prone to weather events and generally less reliable than an installed pipe. Perforation would be prone to clogging from build up so a nonstarter I would expect. Adding flex tubing and a relocation robot would be a maintenance headache as well. Not sure there is an easy optimization.
Ships wouldn't need a long submerged pipe. It'd just need a small hole like a bilge drain or maybe a live well on a fishing boat. Just left the boat cruise around slowly draining back into the ocean.
As for surface life, I'm not oceanographer, but is that really the most vulnerable place? The surface is where fresh water rain meets the ocean, so that would dilute the salinity during storms. However, there's nothing to say that another pump couldn't be pulling from the ocean and mixing the brine into that show it's diluted before and not just pouring brine straight into the ocen
I like this! Though I’m not sure the math works. That page says ideal efficiency for that system would be something like 0.75 kWh/m^3. Compared to 4000 to 5000 kWh/m^3 of diesel. Now we don’t need to be efficient since the point is to use up our “fuel” and we don’t need to cary cargo for this to make sense but with numbers like that, I don’t think our boat will be able to make enough power to move at all.
And it doesn't even need to be a rigid pipe. A flexible pipe made out of, say, waterproof fabric, could be cheaply made to extend miles while remaining open due to the pressure of the water pumped into it.
The brine thing is just a way to shut down conversation and let people feel superior for claiming there are no solutions to our problems except to reduce our standard of living.
It’s obvious you can safely put salt back into the ocean with enough dilution. I bet a middle schooler could design a system to do it.
depends of course, how easy does the brine dissolve, how long does it take that it is so diluted that it can't do any harm, without that information it's not easy to tell
I mean.. we really want to permanently desalinate the ocean somewhat too so putting the brine back seems kinda stupid. Put it on land, let it dry, sell some as table salt and dump the rest into abandoned mines.
This paper is interesting, however, in directly producing crystalline salt, which is lower volume than brine and easier to dispose of, maybe even valuable.
Easy, but not necessarily good for the spot you're pumping concentrated salt back into.
Sure, and enriched uranium comes from the ground, but that doesn't mean it's safe to dump it back in after the enrichment process!
> So just dilute it back to close to ambient salinity using municipal waste water…
Wouldn't it generally be easier to process that municipal waste water, as is already fairly common?
But you're doing that with the same water you're trying to make in the first place!
https://en.wikipedia.org/wiki/Brinicle
https://en.wikipedia.org/wiki/Brine_pool
Just put it on your fries.
Just make prettier-than-Himalayan salt lamps out of it and sell it to hippies. Easy solution.
They're still at lab scale in glass. They haven't built a usable system, even a small one. The big claim here is that it doesn't clog; capillary action moves the salt out of the active area to another area, where some yet to be developed mechanism removes it. That needs to be demonstrated. If they can come up with something that runs for years without clogging or replacing the active material, that's a real advance.
Laser surface preparation is known.[2] It's useful for roughening smooth surfaces in a very structured way, in preparation for painting. The result is a smooth paint surface. If you sandblast to roughen, the first paint layer is somewhat irregular. Then you need to sand and paint again to get a smooth surface. Laser roughening has been tried for auto painting, but didn't go mainstream. A good question here is whether commercial laser surface prep systems can make the material this new process uses.
[1] https://www.nature.com/articles/s41377-026-02315-4
[2] https://www.youtube.com/watch?v=BKYOglHYo_Y
Great book on this BTW: Path Between the Seas. I couldn't put it down.
Another example is ultra black coatings. Those are a forest of tiny black objects arranged so that light gets reflected multiple times and is absorbed. The commercial version is called "Vantablack". It doesn't wear well, but for optical applications such as the insides of camera lenses and telescopes, that's fine.
Sand -> Glass -> heated saltwater -> freshwater + minerals -> ??? -> profit?
Combined with some mangrove farms, surely desert coasts are able to support more life.
Wonder if this is scalable tech, and how quickly it can 'process' water. I guess if they're combined with transparent solar panels, it could be quite an epic tech.
https://news.ycombinator.com/item?id=48349507
Totally underrated area for academic pursuits.
At least in the sciences you have access to lots of opportunities you don’t have at bigger name schools.
They set me up in life in a way that I don’t think would have happened elsewhere.
And who's going to know if you are drinking it or watering your garden?
The reason it doesn't actually work is that it is extremely inefficient. Getting water to condense requires you to somehow reject massive quantities of heat. That's fundamental to physics.
Also, literally anywhere a dehumidifier is reasonably effective, is humid and usually doesn't have such dire water problems. Deserts have extremely low humidity and dehumidifiers working in a desert will produce very little water.
Even a good humidifier in a humid environment is burning KW to generate on the order of ten liters of water a day.
There are a couple places on earth that are essentially deserts but have an early morning humid fog roll through regularly, and those places figured out capturing that water in the air long long before we invented the refrigeration cycle.
It is literally cheaper to desalinate.
Maybe you could build giant greenhouses to fill with sea water and let the sun evaporate the water and collect that with a dehumidifier? Still absurdly inefficient. Water has such an obscene specific capacity for heat that any thermal avenue of separating it from something else will use immense energy.
Who all has access to a femto laser? As far as I know these are all patented, and most of those patents (or at the least companies with rights to production) are in the USA, according to a professor who told us so some years ago in university (in central Europe, but he is quite old already, so I am not sure if his information was 100% up to date; but otherwise I do not doubt the validity of his claim made). So someone is going to milk rather than help. Will be interesting to see what happens to that in some years. My current guesstimate is that nothing will really happen or change.
i'm hoping it doesn't scale, honestly.
Now you ask: why don't we just recover magnesium from brines if it's so great? Magnesium recovery from seawater isn't that easy: typically you have to treat it with some kind of alkali (often Ca(OH)2), so the cost is dominated by the extraction process (your alkali is consumed!), and you're competing with a pretty cheap ore. But if you have a solid byproduct, instead of a liquid, the options for magnesium recovery might be a lot more efficient, potentially offsetting the cost.
The fourth-most-prevalent ion, sulfate, might also be interesting, at least in a hypothetical post-petroleum future where sulfur as a byproduct of fossil fuel extraction is no longer "free". Sulfate is also annoying to extract from seawater, but again if we have a solid, the rules change.
As for the "table" salt itself, I think we'd quickly saturate (!) the market.
Brutal. 𖤐 \m/ 𖤐
“We collected a total of 9.3 g freshwater along with 0.343 g of sea salt from the ABF-STIC with a 9 cm2 surface area over the course of 9 hours. This is equivalent to generating 10.33 liters m−2 of freshwater and 0.38 kg m−2 of sea salt per day. The salinity of the desalinated water is found well below the WHO and EPA standards for safe drinking water.”
However the enclosure system required looks rather complicated and might be sensitive to external temperature (maybe a solar PV-powered cooling loop would help) and I imagine the cost-per-square-meter of the material is rather high, so this looks more like something for emergency response situations or maybe a desal system for a mega-yacht. If it could be scaled the idea is interesting, maybe as lithium separation from concentrated geological brines?
...except for the huge piles of salt.
If the salt was not waste, surely people would already be extracting it from the brine and the existing methods would also be "without waste".
I would like to read more about this from an authoritative source.
https://www.frontiersin.org/journals/marine-science/articles...
https://www.sciencedirect.com/science/article/abs/pii/S14635...
> The brine byproduct wreaks havoc on sea life when it’s deposited back into the ocean by raising the salt level and lowering oxygen in the water.
Managing return of concentrated brine should be entirely tractable in the literal ocean.
Ships (with long submerged pipes) would be prone to weather events and generally less reliable than an installed pipe. Perforation would be prone to clogging from build up so a nonstarter I would expect. Adding flex tubing and a relocation robot would be a maintenance headache as well. Not sure there is an easy optimization.
As for surface life, I'm not oceanographer, but is that really the most vulnerable place? The surface is where fresh water rain meets the ocean, so that would dilute the salinity during storms. However, there's nothing to say that another pump couldn't be pulling from the ocean and mixing the brine into that show it's diluted before and not just pouring brine straight into the ocen
https://en.wikipedia.org/wiki/Osmotic_power
It’s obvious you can safely put salt back into the ocean with enough dilution. I bet a middle schooler could design a system to do it.